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1 article(s) from Feller, Moran

Reversible switching of arylazopyrazole within a metal–organic cage

Anton I. Hanopolskyi,
Soumen De,
Michał J. Białek,
Yael Diskin-Posner,
Liat Avram,
Moran Feller and
Rafal Klajn

Beilstein J. Org. Chem. 2019, 15, 2398–2407, doi:10.3762/bjoc.15.232

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Graphical Abstract

Scheme 1: Reversible photoisomerization of phenylazotrimethylpyrazole 1.

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Figure 1: ¹H NMR spectrum of (E-1)₂ [Graphic 1] 2 (500 MHz, D₂O, 298 K).

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Figure 2: Partial ¹H-¹H NOESY NMR spectrum of (E-1)₂ [Graphic 1] 2 showing NOE correlations between host 2 and guest 1 (50...

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Figure 3: Front view (a) and side view (b) of the X-ray crystal structure of (E-1)₂ [Graphic 1] 2 (major conformations of 1...

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Figure 4: UV–vis absorption spectrum of an aqueous solution of (E-1)₂ [Graphic 1] 2 (blue) and following exposure of this ...

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Figure 5: Top view (a) and side view (b) of the energy-optimized structure of (Z-1) [Graphic 1] 2. Color codes: C, gray; N...

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Figure 6: A series of ¹H NMR spectra of (E-1)₂ [Graphic 1] 2 (500 MHz, D₂O, 298 K) before (bottom) and after exposure to U...

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Figure 7: ¹H NMR and ¹H DOSY spectra of (E-1)₂ [Graphic 1] 2 (500 MHz, D₂O, 298 K) before (left) and after (center) UV irr...

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Figure 8: Palladium-accelerated back-isomerization of Z-1. a) Kinetics of the thermal back-isomerization of Z-...

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Published 10 Oct 2019

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